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The Nature of the Hydrogen Transfer in the Dimethylbenzimidazolycobamide Coenzyme-catalyzed Conversion of 1,2-Propanediol to Propionaldehyde

From the ¹ From the Graduate Department of Biochemistry, Brandeis University, Waltham, Massachusetts 02154

This paper shows that the hydrogen which is removed from C-1 of a particular diol during the conversion to the corresponding aldehyde is not necessarily the same hydrogen which replaces the hydroxyl group of the diol and that therefore the reaction is not necessarily intramolecular.

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