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J. Biol. Chem., Vol. 263, Issue 20, 9576-9577, Jul, 1988

Luminescence of deoxyhemocyanin and deoxytyrosinase

TN Sorrell, M Beltramini and K Lerch
Biochemisches Institut, Universitat Zurich, Switzerland.

The deoxy form of hemocyanins and tyrosinases from certain species displays a weak low-energy luminescence when solutions of the protein are irradiated with light at approximately 290 nm. The emission most likely results from a copper-to-imidazole charge transfer state as shown by studies with a synthetic copper(I) complex having three imidazole ligands.
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